Here is the full list of all 18 Poker Show VR achievements.
Complete the tutorial
Defeat all opponents on easy difficulty
Defeat all opponents on normal difficulty
Defeat all opponents on hard difficulty
Win a hand
Win a hand with two pair
Win a hand with three of a kind
Win 10 hands
Win 20 hands
Win 50 hands
Win 100 hands
Win a hand with flush
Win a hand with straight flush
Win a hand with royal flush
Win a hand with straight
Win a hand with high card
Win a hand with fullhouse
Bluff your opponenet to win a hand