Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Complete three chapters in a row without being killed or reloading a checkpoint.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Live and let die.
Complete game on "FUBAR" difficulty.
Choose restraint.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Save a bullet.
Follow your orders.
Play it smart.
Kill an oryx. (campaign only)
Live and let live.
Carry on, soldier.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
You are relieved.
The end of the line.
Recover all Intel Items.
Kick an enemy by vaulting over a cover. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Choose vengeance.
Kill 350 enemies with any rifle. (campaign only)
Get out of here!
Stand united.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Show mercy.
Sprint into cover 10 times while under fire. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Kill 50 enemies with grenades. (campaign only)
Buck the chain of command.
Play it loose.
Recover 12 Intel Items.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Face the horrors of war.
Kill 75 enemies with any shotgun. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Engineer an exit strategy.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
We have contact.
Kill 100 enemies with any pistol or SMG. (campaign only)
Look out below.
Kill 5 enemies using blind fire. (campaign only)
Kill 3 enemies with a single grenade. (campaign only)
Recover one Intel Item.
What's lost is found.