Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Live and let die.
Complete game on "FUBAR" difficulty.
Recover all Intel Items.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Choose restraint.
Complete game on "Suicide Mission" difficulty.
You are relieved.
Show mercy.
Stun an enemy by dumping sand on their head. (campaign only)
Follow your orders.
Kill 150 enemies with any heavy weapon. (campaign only)
Play it smart.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Complete three chapters in a row without being killed or reloading a checkpoint.
Kill 50 enemies with grenades. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Kill an oryx. (campaign only)
Live and let live.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
Carry on, soldier.
The end of the line.
Kill 75 enemies with any shotgun. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Recover 12 Intel Items.
Choose vengeance.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
Get out of here!
Stand united.
Save a bullet.
Kill 50 enemies with any sniper rifle. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Buck the chain of command.
Play it loose.
Face the horrors of war.
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Engineer an exit strategy.
Kill 3 enemies with a single grenade. (campaign only)
Sprint into cover 10 times while under fire. (campaign only)
We have contact.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
Look out below.
Recover one Intel Item.
What's lost is found.