Here is the full list of all 27 Orcs Must Die! achievements. It takes around 25-30 hours to unlock all of the achievements on Windows.
Earn 5 skulls on every level on War Mage difficulty
Complete Act 3 on Nightmare mode
Complete Act 2 on Nightmare mode
Get 20 chandelier kills in one level
Get 100 acid pot kills in one level
Kill 30,000 orcs
Complete Act 1 on Nightmare mode
Kill an Ogre in a Lava Pit or an Acid Pit
Get a 40 kill streak
Get 300 fireball kills in one level
Win an act 2 or 3 level without using any traps
Get 50 kills with explosive barrels on one level
Get 50 kills with the rolling log in one level
Win a level with 1 rift point left
Complete the Hallway using only the Arrow Wall trap, weapons, and spells
Complete Act 3
Complete Act 2
Kill 10,000 orcs
Get a 30 kill streak
Gib more than 200 enemies on one level
Get 50 pounder kills in one level
Win an act 2 or 3 level using a single trap type
Complete Act 1
Go through portals 20 times in one level
Get a 20 kill streak
Kill 1,000 orcs
Get a 10 kill streak