Here is the full list of all 60 Metal Gear Rising: Revengeance achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Listen to most of the codec conversations.
Set the highest score on every VR Mission.
Acquire all customization items.
Set the highest score on every DL-VR Mission.
Complete every VR Mission.
Complete story mode on Revengeance difficulty with all S rankings.
Destroy a total of 10 Hammerheads during story mode.
While remotely operating a Dwarf Gekko in story mode, find and communicate with all Dwarf Gekkos.
Defeat 100 enemies in DL-Story-01: Brazilian Wind's Story Mode using Quick Draw.
Defeat Sen. Armstrong without taking any damage on Hard difficulty or above.
Destroy a total of 100 Custom Cyborgs during story mode.
Complete DL-Story-01: Brazilian Wind on Revengeance difficulty in one hour or less.
Complete every DL-VR Mission.
In story mode, kill 100 enemies by cutting them.
Successfully complete 50 Executions during story mode.
Successfully complete 10 No Kill battles during story mode.
Defeat 30 enemies in DL-Story-02: Blade Wolf via Hunt Kills.
Complete DL-Story-02: Blade Wolf on Revengeance difficulty in one hour or less.
Destroy a total of 100 Heavily Armed Cyborgs during story mode.
Complete File R-05 in less than 7 minutes.
Complete DL-Story-02: Blade Wolf.
Defeat Khamsin without taking any damage on Hard difficulty or above.
Complete DL-Story-01: Brazilian Wind
Dismember three enemies during Blade Mode with a single attack.
Acquire all enemy officers' left arms.
Destroy a total of 10 Raptors during story mode.
Destroy a total of 5 Vodomjerka during story mode.
Defeat Mistral without taking any damage on Hard difficulty or above.
Destroy a total of 10 Fenrirs during story mode.
Complete File R-07: Assassination Attempt.
Arrive at the objective in File R-07 without being spotted.
Discover all of the soldiers hidden in cardboard boxes.
Acquire all data storage devices.
Unlock every VR Mission.
Destroy all of the humanoid Dwarf Gekkos during story mode.
Complete File R-06: Badlands Showdown.
Defeat Samuel without taking any damage on Hard difficulty or above.
Complete File R-05: Escape From Denver.
Rescue all the civilians.
Destroy a total of 10 Gekkos during story mode.
Complete File R-04: Hostile Takeover.
Defeat Sundowner without taking any damage on Hard difficulty or above.
In story mode, successfully parry 10 attacks in a row in one minute or less.
Successfully complete 50 Zandatsus during story mode.
Cut off the finial at the top of the pagoda in File R-04.
Successfully complete 30 Ninja Kills during story mode.
Destroy a total of 10 Mastiffs during story mode.
Destroy a total of 10 Sliders during story mode.
Complete File R-03: Mile High.
Defeat Monsoon without taking any damage on Hard difficulty or above.
Complete the abandoned railroad sequence in File R-03 without using AR Mode.
Destroy a total of 100 Cyborgs during story mode.
Complete File R-02: Research Facility.
Incapacitate all the soldiers in File R-02 using a Dwarf Gekko.
Destroy all the Gun Cameras in File R-01.
Cut off Metal Gear RAY's metal tail during File R-00.
Complete File R-01: Coup d'État.
Destroy a total of 30 Dwarf Gekkos during story mode.
Complete File R-00: Guard Duty.