Here is the full list of all 97 Divinity: Original Sin 2 achievements. It takes around 200 hours to unlock all of the achievements on Windows.
Learn of the Council of Seven's location from Malady
Complete the game in Tactician Mode
Complete the game in Honour Mode
Share Divinity with The Doctor
Ifan: Forgive Lucian
Make a deal with Adramahlihk
Escape Dallis' siege on the Lady Vengeance without killing every minion
Fane: Embrace this strange new world
Submit to the God King
Fane: Return the Eternals to Rivellon
Successfully walk the Path of Blood
Successfully begin a Game Master session
Beast: Ally with the Queen
Beast: Assassinate the Queen
Convince Alexandar to ally with you
Swear to the Covenant
Discover the hidden entrance to the Academy
Pray at every altar on the Nameless Isle
Sebille: Destroy the Mother Tree
Sebille: Serve the Mother Tree
Sebille: Kill the Master
Use the Curse skill
Destroy every Voidwoken egg in Reaper's Cove
Tame Featherfall
Perform successful surgery on Natalie
Take the ferry to Bloodmoon Island
Set Gareth on a path of vengeance
Escape Dallis' siege on the Lady Vengeance after killing every minion
Successfully begin a match in Arena Mode
Force Dallis to retreat from combat in Fort Joy
Kill Slane
Escort the Black Cat out of Fort Joy
Complete the game in Explorer Mode
Complete the game in Classic Mode
Purge Rivellon of all Source
Share Source with all of Rivellon
Ascend to Divinity
Defeated the Kraken
Ifan: Kill Lucian
Gain entrance to Lucian's Crypt without following the Path of Blood
Persuade Toyseller Sanders to give you his amulet
The Red Prince: Become the father of dragons
The Red Prince: Kill the Red Princess
Rescue Arhu
Lohse: Banish your demon
Defeat Adramahlihk
Lohse: Embrace your demon
Obtain Anathema
Discover Reimond's Lair
Arrive at Arx
Enter The Arena of the One
Shapeshift into every race
Craft a scroll
Craft a grenade
Enter the Academy
Convince all party members to let you ascend
Arrive at the Nameless Isle
Awaken the corrupted Ancestor Tree on Bloodmoon Island
Learn of the Council of Seven's location from The Advocate
Escort Saheila outside without fighting the Lone Wolves
Gain the Villain tag
Learn of the Council of Seven's location from a higher power
Unlock your third Source Point slot
Unlock your second Source Point slot
Set Gareth on a path of reconciliation
Craft a skill
Lockpick your way into Mordus' hidden lair
Serve Garvan the tainted stew
Help free Mari from the Voidwoken
Become champion of the Driftwood Arena
Get caught breaking the law
Kill Andras, the necromantic dog
Speak to an animal's spirit
Correctly answer all of Crispin's questions
Adopt Peeper
Receive Dorotya's kiss
Meet Meistr Siva
Arrive at Reaper's Coast
Enter the Hall of Echoes
Take command of the Lady Vengeance
Welcome Tarquin to the Seekers' service
Kill Radeka
Equip runes to all of an item's available slots
Defeat Alexandar in Fort Joy
Rescue Gareth from Braccus' Armoury
Face a higher power
Arrive at the Sanctuary of Amadia
Kill an enemy using Teleportation
Use your first Source Skill
Remove your Source Collar
Become champion of the Fort Joy arena
Flee Fort Joy for good
Gain the Hero tag
Perform a successful theft
Escape the kraken's clutches
Arrive at Reaper's Eye
Win a persuasion event