Here is the full list of all 50 Black Mesa achievements. It takes around 20-25 hours to unlock all of the achievements on Windows.
Carry the Hidden Hat to Endgame.
Wait too long to jump into the Lambda Teleporter.
Kill all Protozoans in the Borderworld.
Accept G-Man’s offer of employment.
Decline G-Man’s offer of employment.
View the *other* secret ending.
Defeat Nihilanth in under 4 minutes.
Take out all three Healing Crystals in Nihilanth’s Chamber at the same time.
Don't kill any Vortigaunts in the Borderworld.
Complete Interloper without taking any laser damage.
Escape the Gargantua’s Lair without taking any damage from Gargantuas.
Find the snack supply canister.
Find each member of the missing research teams.
Use Cyanogen to kill Gonarch.
Deliver the finishing blow to Gonarch with your Crowbar.
Don't use the Cyanogen and let the Gonarch live.
Get whacked into oblivion in the ledge fight.
Use the welcome mat.
Skip the opening Xen island with a secret jump.
Escape the Hangar in Surface Tension without alerting the Soldiers.
Assemble all the possible Scientists and Guards at the end of Office Complex.
Cook a Grenade for too long.
Die in the AMS Beam before starting the experiment.
Kill a Controller without killing any of its mind-controlled Vortigaunt slaves.
Kill 10 Enemies with Tripmines.
Send the Hidden Hat to Xen.
Drown in Lambda Core's coolant.
Use an entire clip of Gluon ammo in one continuous shot.
Kill 20 enemies with the Hivehand.
Help the Barnacle and Headcrab find true love.
Kill 10 enemies with Snarks.
Get killed by your own Snarks.
Kill an Icthyosaur with either the Tau or Gluon.
Conduct all of the questionable research experiments.
Overcharge it anyway.
Kill an Assassin with the .357 Magnum.
Kill a Barnacle with a Satchel.
Kill a Marine with their own grenade.
Kill a Headcrab using fire.
Refuse to insert the specimen into the Anti-Mass Spectrometer.
Kill 5 enemies with one grenade.
Get overtaken by a Headcrab's ample anterior.
Kill 10 Airborne Headcrabs using the Shotgun.
Headshot 20 enemies with the .357 magnum.
Kill 10 enemies with a reprogrammed Sentry.
Use the alternate path in Office Complex.
Perform surgical caffeine extraction from 20 machines.
Pass the toilet paper to the scientist in need.
Ruin the microwave casserole.
Interfere with the alarm and laptop in Anomalous Materials.