Here is the full list of all 64 Batman: Arkham City - there are Game of the Year Edition achievements.
Obtain 114 medals on the original Arkham City and Nightwing Bundle Pack campaigns (as Nightwing)
Obtain 114 medals on the original Arkham City and Robin Bundle Pack campaigns (as Robin)
Obtain all 108 medals on the original Arkham City campaigns (as Catwoman)
Obtain 78 medals on the original Arkham City and Robin Bundle Pack maps (as Robin)
Obtain 78 medals on the original Arkham City and Nightwing Bundle Pack maps (as Nightwing)
Obtain all 72 medals on the original Arkham City maps (as Catwoman)
Destroy all Harley Balloons
Complete every challenge in Arkham City - Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddlers Revenge (as Batman)
Complete New Game Plus
Obtain all 108 medals on the original Arkham City campaigns (as Batman)
Obtain 72 medals on the original Arkham City campaigns (as Batman)
Obtain 36 medals on the original Arkham City campaigns (as Batman)
Retrieve your stolen goods
Complete all 40 of the Catwoman Riddler grid items
Reveal the mystery watcher
Rescue all the hostages from Riddler
Stop all assaults in Arkham City
Track down the serial killer
Rescue the fifth hostage from Riddler
Perform a perfect combo including all of Batman's combat moves (any play mode)
Obtain all 72 medals on the original Arkham City maps (as Batman)
Complete one combat challenge without taking damage (any character)
Obtain 48 medals on the original Arkham City maps (as Batman)
Collect all of Batman's gadgets and upgrades
Rescue the fourth hostage from Riddler
Rescue the third hostage from Riddler
Reunite the separated couple
Stop the contract operative
Defuse all bombs in 3 minutes or less
Snap Flash an unarmed thug, an armed thug, an environmental object and a Titan
Use 5 different Quickfire gadgets in one fight as Robin in Harley Quinn's Revenge
Zip Kick 5 different thugs
A moment of remembrance
Obtain 24 medals on the original Arkham City maps (as Batman)
The joke's on who?
Clean up the Dry Docks
Find a way into the secret base
Use 5 different Quickfire gadgets in one fight (any play mode)
No crimefighter should be without this
Shield Bash 5 different thugs
Stop the phone booth killer
Rescue the second hostage from Riddler
Destroy it all
All the world is a stage
Don't look down
Steal the score of a lifetime
Fight for survival
Time is running out
A deadly game of hide and seek
We are legion
Uncover the secret of Arkham City
Stop the unstoppable
Last man standing
Clear the airwaves
Rescue the first hostage from Riddler
Have 12 murderous dates with Calendar Man
Solve the first riddle
Complete all augmented reality training exercises
Drop in on an old friend
Hammer the point home
There is only one way in
Save the medical volunteers
Save the damsel, but is she in distress?
Become the Bat